Quinternary phosphate based glasses of up to 2.67 m steroids, deposited by radio frequency magnetron sputtering, were degraded in distilled water and phosphate buffered saline (PBS) to investigate their degradation characteristics. Magnetron sputtered coatings have been structurally compared to their compositionally equivalent melt quenched bulk glass counterparts. The coatings were found to have structurally variable surfaces to melt quenched glass such that the respective bridging oxygen to nonbridging oxygen bonds were 34.2% to 65.8% versus 20.5% to 79.5%, forming metaphosphate (PO3)'(Q2) versus less soluble (P2O7)4′ (Q1) and (PO4)3′ (Q0), respectively.
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